恭喜实验室硕士生连薇与本科生周扬的文章被J Catal接收发表！
发布时间：2025-12-18 14:52:31
Visible-light-driven radical sulfonaminocyclization and sulfonylcyclization of acrylamides with N-sulfonaminopyridinium salts
Jinwei Yuan,a,* Wei Lian,a Yang Zhou,a Meng Yan,a,* Jianli Wu,b Liangru Yang,a Yongmei Xiao,a Lingbo Quc,*
Journal of Catalysis, 2026, 454, 112625.
https://doi.org/10.1016/j.jcat.2025.116625
A photoredox-catalyzed sulfonamination/cyclization reaction of N-alkyl-N-methacryloyl benzamides has been developed, utilizing N-aminopyridinium salts as sulfonamino radical precursors via N-N bond cleavage. Additionally, this reaction also enables efficient N-S bond cleavage to generate diverse sulfonyl radicals through electron donor-acceptor (EDA) complexes, realizing sulfonylation/cyclization of N-alkyl-N-methacryloyl benzamides.
Jinwei Yuan,a,* Wei Lian,a Yang Zhou,a Meng Yan,a,* Jianli Wu,b Liangru Yang,a Yongmei Xiao,a Lingbo Quc,*
Journal of Catalysis, 2026, 454, 112625.
https://doi.org/10.1016/j.jcat.2025.116625
A photoredox-catalyzed sulfonamination/cyclization reaction of N-alkyl-N-methacryloyl benzamides has been developed, utilizing N-aminopyridinium salts as sulfonamino radical precursors via N-N bond cleavage. Additionally, this reaction also enables efficient N-S bond cleavage to generate diverse sulfonyl radicals through electron donor-acceptor (EDA) complexes, realizing sulfonylation/cyclization of N-alkyl-N-methacryloyl benzamides.